I think the realization of the life Liz is leading will eventually hit her if something fatally happens to Paige or to a less extreme, she gets arrested for espionage. They played up the cyanide pill during the season premier. In addition, Phil was the stabilizing point throughout her career and without him Liz may be at her breaking point and if something happens to Paige or she gets caught, she may take the pill as a means to escape, doing it for Mother Russia.
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