While the Riddler maneuvers Batman into being sued, the Dynamic Duo investigate the supervillain's concurrent scheme.

The Riddler fashions a mold of the face of the unconscious Robin. He contacts Batman with two more riddles. The Riddler tells Batman if he can solve the riddles, he'll know where Robin is.

King Boris, who hails from a European country, comes to Gotham City for a visit. Upon his arrival, there is a disturbance, which includes a clue from the Riddler. Batman and Robin investigate and get on the Riddler's trail. They are trapped by the criminal, who ties them to large wheels that will spin with ever-increasing speed until they are dead.

Batman manages to escape the Riddler's death trap. He and Robin decide to lay low until they can figure out the Riddler's caper. Meanwhile, the Riddler frees King Boris, who brings a gift to a major monument in Gotham City. It turns out the Riddler has substituted a bomb for King Boris's gift and he is demanding a ransom. The Riddler, though, overplays his hand, enabling Batman and Robin to capture the Riddler and his gang.

The Riddler's latest scheme involves stealing a wax figure to melt down for its wax that is powerfully corrosive when exposed to direct flame.

Taking advantage of the Riddler's mistaken belief that they were killed escaping his deathtrap, the Dynamic Duo must stop the villain from stealing a treasure of Incan jewels that would mean destroying an archaeological treasure as well.

Charlie Chaplin and the Keystone Kops raid the till at the newly opened Gotham movie theater. The culprits turn out to be 'The Riddler' and his gang in disguise. They lead the Dynamic Duo on a crime spree chase from Mother Gatham's Bakery, past the Gotham Library, and into a Temperance Party. At each of these events, the villains are accompanied by German film maker Van Bloheim who captures everything on celluloid.

Robin has been captured by 'The Riddler', leaving Batman fearing his own reaction. Therefore he asks Commissioner Gordon to accompany him to the Bat-cave to witness his interrogation of Pauline, The Riddler's moll. All clues eventually lead back to the priceless silent film collection of Mr. Van Jones, to which The Riddler is about to add his own silent masterpiece.

"Enter Batgirl, Exit Penguin", is the first episode of Season 3 of the Batman television series', first aired on ABC September 14, 1967 as its ninety-fifth episode. It guest starred Burgess Meredith as The Penguin, and also was the first appearance of Yvonne Craig as Police Commissioner Gordon's daughter, Barbara Gordon, a.k.a. Batgirl.

The Riddler is out to control all of prize fighting in Gotham City. He begins by kidnapping and brainwashing top prizefighters with the aid of the Siren. Then, under the guise of Mushi Nebuchadnezzar, supposed boxing champion of Southwest Asia, he challenges Batman to a fight in the ring. But when it becomes clear that the Riddler has no plans to play fair, it's up to Batgirl to help her crime fighting companions.