Justin has some competition from a popular classmate when he wants to be chosen for the World School Summit at the U.N. Meanwhile, Alex becomes in love with herself due to a potion.

Alex hates being compared to her older brother, Justin, so she asks a genie to remove the resemblences.

Alex and Harper enter an academic competition, but Alex wears "smarty pants" that give her all of the answers. At first it's great, but Alex soon realizes that her cheating doesn't allow Harper to shine. Meanwhile, Max tries to con everybody at school into buying his water bottles.

Alex gets Cupid to help her parents after an argument, but will Cupid cause more trouble than he solves? After being hit by Cupid's arrow, Justin falls in love with Harper.

Alex gets the lead as Tinkerbell in the school's production of Peter Pan but doesn't want the part. So when she enlists the help of a real fairy to sub in and play the part, it causes the production to get out of control and the play is not necessarily performed in the same way as the traditional Peter Pan fairytale!

Max makes up a disease to get out of gym class. Meanwhile, Alex finds out her art teacher is a 16-year-old girl, and turns her back. This results in art, Alex's best subject, being canceled.

After skipping class, the principal places Alex in a "happy helpers" club, however she soon finds out what truly makes the helpers happy. Max's attempt to impress a girl backfires.

Justin decides to use magic to change the weather, but when Mother Nature finds out about it, she begins to cause weather trouble for Justin.

Alex is selected to paint the school's mural, which she is very excited about. However, after using magic to make the mural, she ends up messing up her own artistic ideas.

Justin becomes fed up with Alex constantly going through his stuff and creates a female monster to guard his room and to think like Alex. However Justin's plan backfires when the monster and Alex become fast friends.

Alex starts to date Mason, a transfer student from England. He is perfect in very way with the exception of his view of art. In order to make him a better artist, Alex takes matters into her own hands by putting a spell on him.

Alex has a crush on a boy who won't talk to her because of her sour attitude. She then uses magic to make herself positive. Justin joins the basketball team and tries to capture a big senior year moment on video

Justin’s chances at becoming Student Body President are put in jeopardy after someone wallpapers Principal Laritate’s office with posters from Justin’s campaign and he is accused of masterminding the prank. Meanwhile, Alex befriends Stevie, a rebellious new girl in school, and Jerry, Max and Harper get stuck on a Ferris wheel during their trip to Coney Island.

Harper is desperately trying to remember something, but she cannot. Alex offers to help Harper recall her memory, so she casts a spell on her. Harper then remembers: Stevie is a wizard, and she saw her cast a spell. Alex and Harper confront Stevie, and she confirms their suspisions by casting a spell in the ground that opens up a warp hole and a student falls in. Alex is happy that she has a wizard friend, but Harper feels left out.

When the school's superintendant fires Mr. Laritate because of Alex, Mr. Laritate gets a job at a western place. When the school hires a strict new principal, Alex transports Mr. Laritate back to the Old West in an attempt to show him that it's not what he thought it was and make him want to come back to Tribeca Prep.

Alex sells shirts she makes herself, but Justin makes her give the money to Student Council since she sold them on school grounds without permission. Then when she wins a citizenship award, some feel she does not deserve it.

Alex reveals she has made a clone of Justin and he has been attending college for the past four years. But, when she tries to undo the spell the two Justins to merge into one.

Alex continues her life as a mortal but it causes tension between her and Harper. Meanwhile, a magical robe of Jerry's is found torn into pieces

Alex discovers that Rosie isn't what she seems, and is tricking Justin into doing evil. With the help of angel-in-training Tina, she tries to defeat the plans of the dark angel Gorog. Harper forces Maxine to have a slumber party so that she can live vicariously through her.

Professor Crumbs is planning to check on the Russo's to see how their wizard training is progressing. This causes Alex and Justin to panic since they don't know how to explain "Maxine", and they try to find a way to turn Maxine back to Max. Meanwhile, "America's Got Talent" runner-up Jackie Evancho sings at Tribeca Prep's "Spirit of America Play", which gives Harper a run for her money as she takes the stage for the first time.

Alex, Justin, and Max must get into a Captain Jim Bob Sherwood spaceship in order to destroy an asteroid coming toward the earth.

Mr. Laritate, who lives on a different floor in Alex and Harper's apartment complex, discovers the 13th floor after Mason breaks the elevator, and ends up bitten by a zombie. Meanwhile, Felix's wand is stolen.