Diggle and Felicity travel to the island of Lian Yu in search of Oliver, who left Starling City after the devastation of The Undertaking and his failure to avert it. Convinced to return home, Oliver finds that things are in much worse shape than he imagined – Isabel Rochev is preparing a hostile takeover of Queen Consolidated, Thea refuses to visit Moira in jail, Roy is trying to fill the void left by the Arrow's absence, and Laurel is working with the District Attorney's office to take down the vigilante. Meanwhile, flashbacks to the island show Oliver's mentors Slade, Shado and Oliver in a desperate situation.

Oliver discovers a man who goes by the name “The Mayor” is bringing illegal guns in to The Glades, so Oliver sponsors a “Cash for Guns” event to help clean up the city. Unfortunately, The Mayor crashes the event with his gang and seriously injures Sin. The Canary is furious when she learns her friend is in the hospital and sets out for revenge. Meanwhile, Felicity stuns Oliver with a bit of information about the Canary, Donner asks Laurel to dinner, and Diggle reconnects with an old friend.

A.R.G.U.S. abducts Diggle and asks him to help recover Lyla from a Russian prison. Oliver and Felicity insist on going along to help and Isabel tags along. Meanwhile, Jean Loring advises Thea that her dating Roy is hurting Moira's chance of getting an acquittal.

When a superhumanly strong thief robs a Queen Consolidated warehouse, Central City police scientist Barry Allen comes to Starling City to investigate the case. However, despite his close working relationship with Felicity, Oliver suspects that there's more to the young scientist than meets the eye. Meanwhile, Sin asks Roy to help investigate the disappearance of a friend. In the past, Oliver, Shado, and Sara try to get Slade to the submarine so they can use the serum to save his life.

Sara and Roy become prisoners at the Slade and the only one who is able to save them is Oliver Queen.

When Oliver and his team destroy Slade's centrifuge, he attacks them as Deathstroke to get what he needs to find a replacement. Meanwhile, Laurel ponders what to do with Slade's information, and Oliver tries to convince Thea to help him protect their finances from Isabel.

After the death of someone close to him, Oliver decides to give himself up to Slade rather than risk further bloodshed on his friends and family. Meanwhile, Laurel renews her investigation into Sebastian Blood, and Slade makes his final plans to unleash his Mirakuru-enhanced army on Starling City.

Oliver rallies his team as Slade's soldiers attack the city. Felicity gets a call from S.T.A.R. Labs with game-changing news and Thea comes face-to-face with her father.

As Oliver's face off with Slade escalates, his resolve to the no-kill rule is tested. Especially as Slade targets the woman Oliver loves.